发明名称 |
METHOD OF RECYCLING BY-PRODUCTS OBTAINED FROM PRODUCTION OF WET-PROCESS PHOSPHORIC ACID |
摘要 |
FIELD: chemistry. ^ SUBSTANCE: invention can be used in chemical industry. The method of recycling by-products of production of wet-process phosphoric acid involves treating phosphogypsum with fluorosilicate solution, followed by neutralisation of the mixture and separation thereof by filtration. The fluorosilicate solution used is hydrofluorosilicic acid with concentration of 5-12%. The phosphogypsum is first treated with ammonia water with concentration of 8-12% with ratio of components necessary to obtain liquid to solid phase ratio of (1.5-2.5):1 in the suspension. The hydrofluorosilicic acid is taken in stoichiometric amount with respect to the ammonia added before. The obtained mixture is then neutralised to pH 8-8.8 with ammonia and filtered to separate ammonium sulphate solution and a residue which contains calcium fluoride. ^ EFFECT: invention increases the degree of recycling by-products of production of wet-process phosphoric acid. ^ 1 tbl |
申请公布号 |
RU2462419(C1) |
申请公布日期 |
2012.09.27 |
申请号 |
RU20110119770 |
申请日期 |
2011.05.18 |
申请人 |
OTKRYTOE AKTSIONERNOE OBSHCHESTVO "NAUCHNO-ISSLEDOVATEL'SKIJ INSTITUT PO UDOBRENIJAM I INSEKTOFUNGITSIDAM IM. PROF. JA.V. SAMOJLOVA" (OAO "NIUIF") |
发明人 |
NOROV ANDREJ MIKHAJLOVICH;DOLGOV VIKTOR VASIL'EVICH;MALJAVIN ANDREJ STANISLAVOVICH;BRIZITSKAJA NATAL'JA MITROFANOVNA;BUKKOLINI NATAL'JA VASIL'EVNA;TSIKIN MAKSIM NIKOLAEVICH;GRIBKOV ALEKSEJ BORISOVICH;SHIBANOV EVGENIJ JUR'EVICH |
分类号 |
C01C1/24;C01F11/22 |
主分类号 |
C01C1/24 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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