发明名称 Process for preparing alcohols by hydroformylation of olefins
摘要 In the present invention, there is disclosed a multistage cobalt- or rhodium catalyzed hydroformylation of olefins containing 6 to 24 carbon atoms to alcohols comprising in each stage: a) hydroformylating olefins having a carbon atom content of 6 to 24 carbon atoms in the presence of a cobalt- or rhodium catalyst in a reactor to the point of conversion of olefin reactant to product of 20 to 98 percent; b) removing the catalyst from the resulting liquid discharged from the reactor; c) separating the resulting liquid hydroformylation mixture into a low-boiling fraction comprising olefins and paraffins, and a bottoms fraction comprising aldehydes and/or alcohols; and d) reacting the olefins present in the low-boiling fraction in subsequent process stages comprising steps a), b) and c), and combining the bottoms fractions of process steps c) of all process stages.
申请公布号 CZ303427(B6) 申请公布日期 2012.09.12
申请号 CZ20010002521 申请日期 2001.07.11
申请人 EVONIK OXENO GMBH 发明人 SCHOLZ BERNHARD;NIERLICH FRANZ;KAIZIK ALFRED;HESS DIETER;BUESCHKEN WILFRIED;WIESE KLAUS-DIETHER;ROETTGER DIRK;PROTZMANN GUIDO
分类号 C07C27/22;B01J23/89;C07B61/00;C07C29/141;C07C29/16;C07C31/20;C07C45/50;C07C45/78;C07C47/02;C07C47/12 主分类号 C07C27/22
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