| 摘要 |
A process for producing a purified synthesis gas stream from a feed synthesis gas stream comprising besides the main constituents carbon monoxide and hydrogen also hydrogen sulphide, HCN and/or COS, the process comprising the steps of:
(a) contacting one part of the feed synthesis gas stream with a water gas shift catalyst in a shift reactor in the presence of water/steam to react at least part of the carbon water/steam monoxide with water, to obtain a shifted synthesis gas stream enriched in hydrogen and in carbon dioxide;
(b) contacting another part of the feed gas stream with a hydrolysis catalyst in the presence of water to remove HCN and/or COS to obtain a hydrolysed synthesis gas stream depleted in HCN and/or COS;
(c) removing H 2 S from the shifted synthesis gas stream and from the hydrolysed synthesis gas stream by contacting these gas streams in a H 2 S-removal zone with an aqueous alkaline washing liquid to obtain a H 2 S-depleted synthesis gas stream and a sulphide-comprising aqueous stream;
(d) contacting the sulphide-comprising aqueous stream with sulphide-oxidizing bacteria in the presence of oxygen in a bioreactor to obtain a sulphur slurry and a regenerated aqueous alkaline washing liquid;
(e) removing carbon dioxide from the H 2 S-depleted synthesis gas stream, to obtain the purified synthesis gas stream. |
