发明名称 |
METHOD FOR PRODUCING ß-FLUOROALCOHOL |
摘要 |
This method for producing a ß-fluoroalcohol comprises a step wherein an a-fluoroester is caused to react with a hydrogen gas (H2) in the presence of a specific ruthenium complex (one represented by general formula (2), especially one represented by general formula (4)). The production method is capable of employing a suitable hydrogen pressure of 1 MPa or less by virtue of the usage of a specific ruthenium complex, and thus does not require a high-pressure gas production facility when put in industrial practice. In addition, the present invention is capable of remarkably reducing the amount of catalyst used therein (base material/catalyst ratio = 20,000) in comparison to the base material/catalyst ratio (1,000) in conventional reduction of an a-fluoroester. Since the hydrogen pressure and the amount of catalyst used in this production method are reduced, the production cost of a ß-fluoroalcohol can be significantly reduced. |
申请公布号 |
WO2012105431(A1) |
申请公布日期 |
2012.08.09 |
申请号 |
WO2012JP51765 |
申请日期 |
2012.01.27 |
申请人 |
CENTRAL GLASS COMPANY, LIMITED;ISHII, AKIHIRO;OOTSUKA, TAKASHI;ISHIMARU, TAKEHISA;IMAMURA, MARI |
发明人 |
ISHII, AKIHIRO;OOTSUKA, TAKASHI;ISHIMARU, TAKEHISA;IMAMURA, MARI |
分类号 |
C07C29/149;B01J31/24;C07B61/00;C07C31/38;C07C31/42;C07C33/42;C07C33/46;C07D213/30 |
主分类号 |
C07C29/149 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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