发明名称 METHOD FOR PRODUCING ß-FLUOROALCOHOL
摘要 This method for producing a ß-fluoroalcohol comprises a step wherein an a-fluoroester is caused to react with a hydrogen gas (H2) in the presence of a specific ruthenium complex (one represented by general formula (2), especially one represented by general formula (4)). The production method is capable of employing a suitable hydrogen pressure of 1 MPa or less by virtue of the usage of a specific ruthenium complex, and thus does not require a high-pressure gas production facility when put in industrial practice. In addition, the present invention is capable of remarkably reducing the amount of catalyst used therein (base material/catalyst ratio = 20,000) in comparison to the base material/catalyst ratio (1,000) in conventional reduction of an a-fluoroester. Since the hydrogen pressure and the amount of catalyst used in this production method are reduced, the production cost of a ß-fluoroalcohol can be significantly reduced.
申请公布号 WO2012105431(A1) 申请公布日期 2012.08.09
申请号 WO2012JP51765 申请日期 2012.01.27
申请人 CENTRAL GLASS COMPANY, LIMITED;ISHII, AKIHIRO;OOTSUKA, TAKASHI;ISHIMARU, TAKEHISA;IMAMURA, MARI 发明人 ISHII, AKIHIRO;OOTSUKA, TAKASHI;ISHIMARU, TAKEHISA;IMAMURA, MARI
分类号 C07C29/149;B01J31/24;C07B61/00;C07C31/38;C07C31/42;C07C33/42;C07C33/46;C07D213/30 主分类号 C07C29/149
代理机构 代理人
主权项
地址