摘要 |
<P>PROBLEM TO BE SOLVED: To provide a new optically active macrocyclic compound capable of identifying asymmetry of an asymmetric compound, especially, capable of identifying asymmetry of an asymmetric compound incapable of hydrogen-bonding, to provide a production method for such optically active macrocyclic compound, and to provide an optical purity determination reagent and an optical purity determination method using the same. <P>SOLUTION: There is provided an optically active macrocyclic compound represented by general formula (1). [In the formula, X represents a bivalent aromatic group containing a porphyrin ring; Y represents O, S or a 1C-10C bivalent organic group containing no aromatic ring; Z represents H, a 1C-20C univalent organic group, nitro, (protected) amino, azide or a halogen; and * represents axial asymmetry of binaphthyl]. <P>COPYRIGHT: (C)2012,JPO&INPIT |