| 摘要 |
A chlorine-containing product is obtained by reacting N-(b -hydroxypropyl)-carbazole with thionyl chloride.ALSO:A polymeric photoconductive composition contains a polymeric reaction product as below, with or without the various additives mentioned in Specification 964,875, i.e. sensitisers, plasticizers, pigments, and agents controlling viscosity, free flow, ageing, oxidation, thermal stability and gloss; the polymeric products are those made by reacting (a) a polymer with a halogen-containing aromatic or heterocyclic compound, (b) a halogen-containing polymer with an aromatic or heterocyclic compound, or (c) a polymer and an aromatic or heterocyclic compound with a di- or poly-halogen compound. Details are given of the reactions of (a) polystyrene with N-(b -chloropropyl)-carbazole, and (b) polyvinyl chloride with fluorene, naphthalene and toluene. Other specified reactants are: chlorinated polyvinyl chloride, polyvinylbenzyl bromide, polyisophenylbenzyl bromide and a copolymer of vinyl chloride and styrene; anthracene, carbazole, phenthiazine, phenoxathiine, acridine, lophine and derivatives thereof. The di-halogen compound for method (c) may be a methylene halide, ethylene dibromide or chloroacetyl chloride. A Friedel-Crafts catalyst is used for each reaction. Suitable solvents for casting the products on to a support are methylene chloride, chloroform, carbon tetrachloride, dimethylformamide, acetone, benzene, tetrahydrofuran and mixtures thereof. Other synthetic resins may be present in the compositions, e.g. polyvinylcarbazole and a terpolymer of vinyl chloride, vinyl acetate and maleic anhydride. In particular, the polymeric photoconductors of Specifications 964,871, 964,875 and 964,877 may be present. Specification 964,778 also is referred to. The Provisional Specification states that the substances mentioned in Specifications 883,787, 883,788, 964,873, 964,874 and 964,872 may also be present.
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