发明名称 PROCESS FOR PRODUCTION OF 5-PHENYLISOPHTHALIC ACID
摘要 The present invention provides an industrially advantageous process for producing 5-phenylisophthalic acid, which process attains excellent selectivity and yield and also realizes recovery and reuse of a catalyst. The process for producing 5-phenylisophthalic acid represented by formula (1) is characterized in that the process includes the following steps (A) to (C): (A) reacting m-xylene with cyclohexene in the presence of hydrogen fluoride and boron trifluoride, to thereby produce 1-cyclohexyl-3,5-dimethylbenzene; (B) dehydrogenating the 1-cyclohexyl-3,5-dimethylbenzene produced in step (A) in the presence of a dehydrogenation catalyst, to thereby produce 3,5-dimethylbiphenyl; and (C) dissolving the 3,5-dimethylbiphenyl produced in step (B) in a solvent and oxidizing the 3,5-dimethylbiphenyl in the co-presence of an oxidation catalyst, to thereby produce 5-phenylisophthalic acid.
申请公布号 EP2003111(B1) 申请公布日期 2012.07.04
申请号 EP20070740984 申请日期 2007.04.04
申请人 MITSUBISHI GAS CHEMICAL COMPANY, INC. 发明人 NISHIUCHI, JUNYA
分类号 C07C51/265;C07C2/70;C07C5/367;C07C13/28;C07C15/14;C07C63/331 主分类号 C07C51/265
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