Process for the manufacture of polybasic araliphatic carboxylic acids and of derivatives thereof

摘要

Polybasic araliphatic carboxylic acids and derivatives thereof are produced by heating fatty acids (or derivatives thereof) containing conjugated double bonds with aromatic vinyl compounds in a molar ratio of 1:0.2-5, in the absence of free radical forming catalysts and in the presence of an inhibitor for free radical catalysts, to 50-150 DEG C. until the viscosity of the mixture is constant and then for at least 1 hour to 180-200 DEG C. The acids may be eleostearic, licanic, dehydrogenated castor oil or an isomerized acid as described in Specification 925,148. The acid derivatives may be esters of the fatty acids with C1- 4 monohydric alcohols or glycerides or fats (a number are specified) containing such glycerides of the fatty acids which after heating with the vinyl compound are converted by alcoholysis to esters. The vinyl compound may be styrene, a -methyl styrene or vinyl-toluene. The reactants may be heated in the presence of other fatty acids, e.g. mono-unsaturated and unconjugated unsaturated. The inhibitor may be hydroquinone or butyl pyrocatechol and a catalyst for cationic polymerization may also be used, e.g. mineral acids, sulphonic acids, cation exchangers in acid form or Friedel-Crafts catalysts. The reactants may be heated in a solvent e.g. toluene or xylene. Any unreacted acids or vinyl compounds, and vinylated monocarboxylic acids and solvents may be removed by distillation. The products may be reacted with polyalcohols or polyamines and may be used for the manufacture of lacquers, foils, seals and adhesives.