发明名称 GLYCERIN DEHYDRATION CATALYST AND METHOD OF PRODUCING ACROLEIN USING THE SAME, METHOD OF PRODUCING ACRYLIC ACID, AND METHOD OF PRODUCING HYDROPHILIC RESIN
摘要 <P>PROBLEM TO BE SOLVED: To provide a glycerin dehydration catalyst reducing formation of propionaldehyde as a by-product, allowing highly efficient production of acrolein, and allowing long-term maintenance of catalyst performance, and a method of producing acrolein using the same, a method of producing acrylic acid, and a method of producing hydrophilic resin. <P>SOLUTION: The glycerin dehydration catalyst contains rare earth metal salt of phosphoric acid and the molar ratio P/R of the phosphorus (P) to rare earth metal (R) is more than 1.0 and less than 1.5. In the method of producing acrolein, glycerin is dehydrated to obtain the acrolein under the presence of the catalyst. In the method of producing acrylic acid, the obtained acrolein is oxidized to obtain the acrylic acid. In the method of producing hydrophilic resin, a monomer component containing the obtained acrylic acid is polymerized. <P>COPYRIGHT: (C)2012,JPO&INPIT
申请公布号 JP2012091157(A) 申请公布日期 2012.05.17
申请号 JP20110070997 申请日期 2011.03.28
申请人 NIPPON SHOKUBAI CO LTD 发明人 OKADA MASAKI
分类号 B01J27/18;C07B61/00;C07C45/52;C07C47/22;C07C51/235;C07C57/055 主分类号 B01J27/18
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