| 摘要 |
1,227,007. # - Halogeno - substituted organic isocyanates. FARBWERKE HOECHST A.G. 9 May, 1968 [9 May, 1967], No. 22055/68. Heading C2C. #-Halogeno-substituted organic isocyanates of general formula where X is Cl or Br and R 1 , R 2 , R3 and R 4 are each H, C 1-18 alkyl or alkenyl, cyclo-alkyl or cycloalkenyl of up to 8 C atoms, aralkyl, aryl or heterocyclic groups, which may be inertly substituted, or two of R 1 , R 2 , R 3 and R 4 together represent alkylene or alkenylene of up to 6 C atoms or part of a polycyclic carbocyclic or heterocyclie ring system of up to 18 C atoms, optionally containing a second #-halogenosubstituted isocyanate group, are prepared by rearrangement at - 30‹ to + 250‹ C. of a lactam of general formula where the symbols are as above, with the proviso that a second N-halogeno-substituted lactam ring can form the aforesaid second #- halogeno-substituted NCO group, in the presence of a free radical-forming catalyst and, as co-catalyst, an ethylenically or acetylenically unsaturated compound containing no functional group which reacts with the NCO group. The #-bromo-substituted products are claimed " per se". An ethylenically or acetylenically unsaturated B-lactam of the formula above may be used as both reactant and co-catalyst. The reaction may be effected in a solvent or solvent mixture. The #-bromo-substituted products in which R 1 , R 2 , R 3 and R 4 are each H, alkyl, haloalkyl or alkenyl of up to 4 C atoms, cycloalkyi of up to 8 C atoms or phenyl, or two of the radicals together represent alkylene or alkenylene of up to 6 C atoms or are a part of a polycyclic hydrocarbon ring system of up to 13 C atoms, are also claimed " per se ". |
