Methods and apparatuses for producing styrene from ethylbenzene

摘要

Embodiments of methods and apparatuses for producing styrene are provided. The method comprises the steps of introducing ethylbenzene to a first dehydrogenation reactor containing a first high activity dehydrogenation catalyst at a first predetermined inlet temperature to form a first intermediate effluent stream that comprises styrene, ethylbenzene, and hydrogen. Oxygen is added to the first intermediate effluent stream to form a first oxygenated intermediate effluent stream. The first oxygenated intermediate effluent stream is introduced to a first oxidation-reheat dehydrogenation reactor at a second predetermined inlet temperature of about 530° C. or less to form styrene. The first oxidation-reheat dehydrogenation reactor contains a first oxidation catalyst and a second high activity dehydrogenation catalyst.