发明名称 |
PROCESS FOR MAKING ETHYLENE POLYMER BLENDS WITH CONTROLLED LONG-CHAIN BRANCHING |
摘要 |
A high-temperature solution process for making an ethylene polymer blend having a controlled degree of long-chain branching is disclosed. Ethylene is polymerized in the presence of a first Ziegler-Natta catalyst comprising titanium, magnesium, and aluminum in the absence of hydrogen to produce a first ethylene polymer component having substantial long-chain branching. A second ethylene polymer component having little or no long-chain branching is also prepared. Both polymerizations are performed at a temperature from 140°C to 250°C. The first and second ethylene polymer components are combined to give a polymer blend. The degree of long-chain branching in the blend is controlled by adjusting the relative amounts of the first and second ethylene polymer components. The invention enables the preparation of valuable products having a pre-determined degree of long-chain branching using readily available Zeigler-Natta catalysts, commercially practiced techniques, and conventional equipment. |
申请公布号 |
CA2757249(A1) |
申请公布日期 |
2012.05.08 |
申请号 |
CA20112757249 |
申请日期 |
2011.11.03 |
申请人 |
EQUISTAR CHEMICALS, LP |
发明人 |
LYNCH, MICHAEL W.;KLUG, KENNETH J. |
分类号 |
C08L23/04;C08F2/04;C08F4/658 |
主分类号 |
C08L23/04 |
代理机构 |
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