发明名称 |
LITHIUM-ION SECONDARY BATTERY |
摘要 |
Disclosed is a lithium-ion secondary battery which includes a carbonaceous material in an anodic active material mix, and a cyclic carbonate and a chain carbonate both in an electrolytic solution. The solvent contains an additive which is a substance having a LUMO energy determined through molecular orbital calculation of lower than the LUMO energy of ethylene carbonate determined through molecular orbital calculation and having a HOMO energy lower than the HOMO energy of vinylene carbonate determined through molecular orbital calculation, the electrolytic solution contains LiPF 6 or LiBF 4 as an electrolyte, and the electrolytic solution shows a reduction-reaction current of -0.05 mA/cm 2 (provided that a reaction current on the reducing side be negative) or less at a potential lower than 1 V and shows an oxidation-reaction current of 0.5 mA/cm 2 (provided that a reaction current on the oxidizing side be positive) or more at a potential higher than 5. 7 V in an LSV measurement at a potential sweep rate of 1 mV/s using a glassy-carbon disk electrode as a working electrode, a platinum electrode as a counter electrode, and a lithium electrode as a reference electrode. |
申请公布号 |
EP2448056(A1) |
申请公布日期 |
2012.05.02 |
申请号 |
EP20100791831 |
申请日期 |
2010.06.21 |
申请人 |
HITACHI VEHICLE ENERGY, LTD. |
发明人 |
INOUE, RYO;TSUBOUCHI, SHIGETAKA;OKUMURA, TAKEFUMI |
分类号 |
H01M10/0567;H01M4/505;H01M4/525;H01M4/587;H01M10/0525;H01M10/0569 |
主分类号 |
H01M10/0567 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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