| 摘要 |
Azide compositions selected from i) UOCR2CR2N3 wherein U is D, or a urethane (—CO—NR2) and R is independently H, D, or an organic group; ii) R′2NCR2CR2N3 or A-R′3NCR2CR2N3 wherein R′ is an organic group and A is an anion; or iii) G(N3)m wherein m is an integer from 2 to about 10 and G is a m-valent organic group wherein at least two of the azido groups are connected via aliphatic carbon atoms wherein G may contain organic groups, and uses thereof are described. Specifically, the azide compositions selected from the group consisting of: N3CH2CH2OCH2CHOHCH2N3, CH3OCH2CHOHCH2N3, CH3OCH2CH(OCONHC4H9)CH2N3, N3CH2CH2O[CH2CH(CH2N3)O]6H, CH3CH2C[CH2(OCH2CH(CH2N3))2OCOCH3]3N3CH2CH2OCONH(CH2)6NHCOOCH2CH2N3, (CH3)3CNHCOOCH2CH2N3, n-C4H9NDCOOCH2CH2N3, C6H5N—HCOOCH2CH2N3, C4F9OCFCF3NDCOOCH2CH2N3, DOCH2CH2N3, and [(CH3)3NCH2CH2N3]+I are described. |
