发明名称 METHOD OF PRODUCING (METH)ACRYLATES OF TETRA- OR MORE POLYBASIC ALCOHOLS
摘要 FIELD: chemistry. ^ SUBSTANCE: invention relates to an improved method of producing high-purity acrylic and methacrylic esters, obtained via reesterification of (meth)acrylic esters of formula I , where R1 is hydrogen or methyl and R2 is an alkyl residue with 1-40 carbon atoms, with alcohols containing four or more esterifiable hydroxyl groups and selected from a group of tetrabasic alcohols of formula II: R'"(OH)n, where n ëÑ 4 and R"' denotes, if necessary, a branched aliphatic or aromatic radical wiht 4-40 carbon atoms, in the presence of lithium amide as a reesterification catalyst, taken in amount of 0.01-10 wt % per total weight of the reaction mixture. ^ EFFECT: improved method of producing high-purity acrylic and methacrylic esters. ^ 4 cl, 3 ex
申请公布号 RU2446144(C2) 申请公布日期 2012.03.27
申请号 RU20080114030 申请日期 2006.08.16
申请人 EHVONIK REM GMBKH 发明人 SHMITT BARDO;KNEBEL' JOAKHIM;GREHFF GJUNTER
分类号 C07C67/03;C07C69/54 主分类号 C07C67/03
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