发明名称 Tetrahydrobenzoxazines
摘要 Use of tetrahydrobenzoxazine compound (I) as stabilizers for the stabilization of dead organic materials against light, oxygen and heat. Use of tetrahydrobenzoxazine compound of formula (I) as stabilizers for the stabilization of dead organic materials against light, oxygen and heat. R 1> : 1-3000C hydrocarbyl (interrupted by one or more heteroatoms of O or S, and one or more NR 6>); R 6> : H or 1-4C alkyl; either R 2>, R 3>, R 5> : H, OH or 1-3000C hydrocarbyl (interrupted by one or more heteroatoms of O or S, and one or more NR 6>); and R 4> : H, OH or 1-3000C hydrocarbyl (interrupted by one or more heteroatoms of O or S, and one or more NR 6>); or R 4> : benzoxazine compound of formula (II), benzoxazine compound of formula (III) or (III-a); or R 2>+R 3> with benzol, R 3>+R 4> with benzol, R 4>+R 5> with benzol : O-CH 2-NR 7>-CH 2, O-CH 2-NR 8>-CH 2 or tetrahydro oxazine ring; X : hydrocarbon bridge containing one or more isobutene units; R 10>, R 11> : H or 1-10C-akyl; and R 7>, R 8> : 1-3000C hydrocarbyl (interrupted with one or more heteroatom of O or S, and one or more NR 6>). Where at least R 1>-R 8> has 4-3000C atoms and the remaining groups has 1-20C atoms. Independent claims are included for: (1) turbine fuel composition comprising a turbine fuel (jet fuel) and at least (I); (2) an additive concentrate for turbine fuels comprising (I), optionally at least a diluent and an additive; (3) a preparation of (I) comprising reacting substituted phenol, benzcatechin, resorcin, hydroquinone, phloroglucin or hydroxyhyroquinone with one mole of primary amine of formula (R 1>NH 2), (R 7>-NH 2) or (R 8>-NH 2), and two mole of formaldehyde or formaldehyde-free substance and two mole of alcohol of formula (R 9>-OH) in the presence of nitrogen reagent of formula (R 9>-O-CH 2-N(A)-CH 2-O-R 9>); and (4) tetrahydrobenzoxazine compound (I). A : R 1> or R 7>; and R 9> : 1-8C alcohol. [Image] [Image].
申请公布号 EP2239258(B1) 申请公布日期 2012.03.14
申请号 EP20100167054 申请日期 2006.07.18
申请人 BASF SE 发明人 LANGE, ARNO;MACH, HELMUT;RATH, HANS PETER;POSSELT, DIETMAR
分类号 C07D265/16;C07D498/04;C09K15/20;C10L1/22;C10M133/48 主分类号 C07D265/16
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