发明名称 |
Electrochemical process and cell for the preparation of germane |
摘要 |
The invention relates to the electrolysis of aqueous electrolyte solutions containing GeO 2 ; hydroxide and water with metal alloy electrodes, such as copper or tin rich alloy electrodes with alloying elements such as Sn, Pb, Zn, Cu etc, to generate Germane (GeH 4 ). Cu-rich alloy electrodes have been demonstrated to increase the GeH 4 current efficiency by almost 20 % compared to Cu metal electrodes. Germanium deposition has been found to be either absent or minimal by using Cu-rich alloy electrodes. Several different methods for maintaining the cell performance or restoring the cell performance after a reduction in current efficiency over time have been identified. A titration-based method for the analysis of the electrolyte to obtain the concentration of GeO 2 and the concentration of hydroxide is also disclosed. |
申请公布号 |
EP2426235(A2) |
申请公布日期 |
2012.03.07 |
申请号 |
EP20110179721 |
申请日期 |
2011.09.01 |
申请人 |
AIR PRODUCTS AND CHEMICALS, INC. |
发明人 |
JAMBUNATHAN, KRISHNAKUMAR;BERGER, KERRY RENARD;MACHADO, REINALDO MARIO;RAGSDALE, DANIEL JAMES |
分类号 |
C25B1/00;C25B9/08 |
主分类号 |
C25B1/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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