发明名称 HYDROFORMYLATION PROCESS WITH DOUBLY OPEN-ENDED BISPHOSPHITE LIGAND
摘要 A continuous hydroformylation process for producing at least one aldehyde product by utilizing a transition metal and a ligand mixture comprising an organopolyphosphite and an organomonophosphine, with improved stability of the organopolyphosphite ligand. The process involves reacting one or more olefinically-unsaturated compounds with carbon monoxide and hydrogen in the presence of an organopolyphosphite ligand and an organomonophosphine ligand, at least one of such ligands being bonded to a transition metal to form a transition metal-ligand complex hydroformylation catalyst. Surprisingly the addition of the organomonophosphine to a Rh/organopolyphosphite catalyst system did not result in a significant loss of reaction rate.
申请公布号 US2012029242(A1) 申请公布日期 2012.02.02
申请号 US200913260572 申请日期 2009.12.10
申请人 BRAMMER MICHAEL A. 发明人 BRAMMER MICHAEL A.
分类号 C07C45/50 主分类号 C07C45/50
代理机构 代理人
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