| 摘要 |
There are disclosed urethane acrylates of Formula 1: where R1a, R1b and R1c each independently represent C2-15hydrocarbylene, preferably linear C3-12alkylene (such as, C4-8alkylene; e.g. hexylene); a isophorone unit and/or a tolyl unit. R2a, R2b and R2c each independently represent: a divalent moiety of (Formula 2) where X and Y independently represent C2-10hydrocarbylene, preferably C2-8alkylene; and k is from 0 to 30; l is from 0 to 30; and ‘k+l’ is from 1 to 30; and/or a divalent moiety of Formula 3 where V and W independently represent C2-10hydrocarbylene, preferably C2-8alkylene; and i is from 0 to 30; j is from 0 to 30; and ‘i+j’ is from 1 to 30; p is from 1 to 10; and r is from 1 to 10; and R3a R3b and R3c each independently represent H or methyl (i.e. R3 forms respectively part of an acrylate or a methacrylate group); with the provisos that at least one of R2a, R2b and R2c is a moiety of Formula 2; at least one of R2a, R2b and R2c is a moiety of Formula 3; and when R2 represents a divalent moiety of Formula 3, the sub moiety within Formula 3, is attached directly to the amide group in Formula 1. The UAs of Formula 1 are of non crystalline and of low viscosity and are suitable for preparing polymeric flexibilizers suitable for tenting applications. A process for preparing these urethane acrylate is also described. |
