| 摘要 |
FIELD: chemistry. ^ SUBSTANCE: method involves reaction of 1-chloroadamantane with ethylidene diacetate (EDA), where the catalyst used is a manganese-containing compound selected from Mn(acac)3 or Mn(OAc)2 or Mn2(Co)10, activated with acetonitrile in a tetrachloromethane medium in molar ratio [1-chloroadamantane] : [EDA] : [CCl4] : [catalyst] : [CH3CN]=100 : 100-200 : 200 : 3-5 : 10-15 at temperature 160-180C for 5-7 hours. Under optimum conditions with 85-90% conversion of 1-chloroadamantane, the only reaction product is 1-acetyladamantane. ^ EFFECT: improved method. ^ 1 tbl, 8 ex |
