| 摘要 |
This invention relates to a Fe-based catalyst for Fischer-Tropsch synthesis, preparation method and application thereof. The catalyst contains Fe, oxide(s) of IB group metal Cu and/or Ag as a reducing promoter, IA group metal Li, Na, K or Rb as an electron promoter, VIII group noble metal Ru, Rh, Pd or Pt as a hydrogenation promoter and SiO2 as a structure promoter. The preparation method comprises the following steps: preparing a solution of Fe salt; co-precipitating the solution rapidly with an alkaline compound, then washing and pulping again; and adding a solution of IB group metal salt as a reducing promoter, a IA group metal salt solution and silica sol, or adding a solution of IB group metal salt as a reducing promoter and a silicate of IA group metal; then molding by spray-drying, impregnating in a solution of VIII group noble metal salt, and drying and roasting to obtain the catalyst. The catalyst is suitable for producing hydrocarbons by a low temperature Fischer-Tropsch synthesis process. The process has a high yield of heavy hydrocarbons and a low selectivity to methane and significantly reduces the selectivity to olefins. |
