<p>A process for making a Ziegler-Natta-type catalyst precursor including contacting a Group 4 metal compound with one or more Titanium compounds selected from the group of TiCl3 (A1-activated or hydrogen-reduced), and Ti(OR)4 where R is ethyl, isopropyl or butyl in the presence of an alcohol solution having at least one C2-C4 alcohol and at least one of MgCl2 and magnesium compounds which form MgCl2 in the presence of the alcohol solution to form a catalyst precursor solution is provided. Also provided are catalysts made from the precursors produced by the process. Also provided are polymers made using the catalysts.</p>
申请公布号
WO2011130415(A1)
申请公布日期
2011.10.20
申请号
WO2011US32330
申请日期
2011.04.13
申请人
UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY LLC;JORGENSEN, ROBERT, JAMES;WAGNER, BURKHARD, E.