发明名称 METHOD FOR DIRECTLY PRODUCING PHOSPHINE DERIVATIVE FROM PHOSPHINE OXIDE DERIVATIVE
摘要 <p>Disclosed is a method for producing a phosphine derivative represented by formula (2), which is characterized in that a phosphine oxide derivative represented by formula (1) is subjected to an electrolytic reduction reaction using a trialkylsilyl halide in a polar organic solvent in the presence of a supporting electrolyte. (In formulae (1) and (2), Ar represents an aryl group that is selected from the group consisting of phenyl groups, phenyl groups having a substituent, heteroaromatic ring groups, and heteroaromatic ring groups having a substituent; R represents an aliphatic hydrocarbon group or an aliphatic hydrocarbon group having a substituent; and n represents an integer of 0-3.) ArnR3-nP=O (1) ArnR3-nP (2)</p>
申请公布号 WO2011129442(A1) 申请公布日期 2011.10.20
申请号 WO2011JP59414 申请日期 2011.04.15
申请人 NATIONAL UNIVERSITY CORPORATION OKAYAMA UNIVERSITY;KAWAKUBO HIROMU;TANAKA HIDEO;KUROBOSHI MANABU;YANO TOMOTAKE 发明人 KAWAKUBO HIROMU;TANAKA HIDEO;KUROBOSHI MANABU;YANO TOMOTAKE
分类号 C25B3/04;C07F9/50 主分类号 C25B3/04
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