发明名称 Aqueous Polymerization of Fluorinated Monomer Using Polymerization Agent Comprising Fluoropolyether Acid or Salt and Short Chain Fluorosurfactant
摘要 A process comprising polymerizing at least one fluorinated monomer in an aqueous medium containing initiator and polymerization agent to form an aqueous dispersion of particles of fluoropolymer, the polymerization agent comprising: fluoropolyether acid or salt thereof having a number average molecular weight of at least about 800 g/mol; and fluorosurfactant having the formula: [R1—On-L-A−]Y+ wherein: R1 is a linear or branched partially or fully fluorinated aliphatic group which may contain ether linkages; n is 0 or 1; L is a linear or branched alkylene group which may be nonfluorinated, partially fluorinated or fully fluorinated and which may contain ether linkages; A− is an anionic group selected from the group consisting of carboxylate, sulfonate, sulfonamide anion, and phosphonate; and Y+ is hydrogen, ammonium or alkali metal cation; with the proviso that the chain length of R1—On-L- is not greater than 6 atoms.
申请公布号 US2011251317(A1) 申请公布日期 2011.10.13
申请号 US201113167000 申请日期 2011.06.23
申请人 E. I. DU PONT DE NEMOURS AND COMPANY 发明人 BROTHERS PAUL DOUGLAS;GANGAL SUBHASH VISHNU
分类号 C08F2/20;C08K5/095;C08K5/42;C08L27/18 主分类号 C08F2/20
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