摘要 |
<p>Polyurethane elastomer articles formed from prepolymer mixtures having free diphenylmethane diisocyanate (MDI) content from 2.0 to 5.0 wt %, based on the weight of the prepolymer mixture. The prepolymer mixtures comprise a polyester, polyether, or polycaprolactone (PCL) prepolymer and MDI. The polyurethane elastomer articles are formed by curing the prepolymer mixture with a chain extender, such as a curative comprising a methylenedianiline-sodium chloride complex. The articles have good physical properties that may weigh over 225 kg, and have a three-axis thickness greater than 10.2 cm.</p> |