发明名称 |
METHOD FOR ALLYLATING AND VINYLATING ARYL, HETEROARYL, ALKYL, AND ALKENE HALOGENIDES USING TRANSITION METAL CATALYSIS |
摘要 |
The invention relates to a method for producing organic compounds of the general formula (I) R-R' (I), by reacting a corresponding compound of the general formula (II) R-X (H), where X stands for fluorine, chlorine, bromine, or iodine, forming a magnesium organic compound of the general formula (III) [M+]n [RmMgXkY1] (III), compounds of the formula (III) being reacted with a compound of the general formula (IV), characterized in that the reaction of (III) with (IV) is performed in the presence of a) catalytic quantities of an iron compound, relative to the compound of the general formula (II), and optionally in the presence b) of an additive comprising nitrogen, oxygen, and/or phosphorous in a catalytic or stoichiometric quantity relative to the compound of the general formula (II). |
申请公布号 |
WO2011098375(A2) |
申请公布日期 |
2011.08.18 |
申请号 |
WO2011EP51390 |
申请日期 |
2011.02.01 |
申请人 |
SALTIGO GMBH;GOTTA, MATTHIAS;LEHNEMANN, BERND WILHELM;CZAPLIK, WALDEMAR MAXIMILIAN;MAYER, MATTHIAS;JACOBI VON WANGELIN, AXEL |
发明人 |
GOTTA, MATTHIAS;LEHNEMANN, BERND WILHELM;CZAPLIK, WALDEMAR MAXIMILIAN;MAYER, MATTHIAS;JACOBI VON WANGELIN, AXEL |
分类号 |
C07B49/00 |
主分类号 |
C07B49/00 |
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