发明名称 |
A SEMI-CONTINUOUS PROCESS FOR THE SYNTHESIS OF A CATALYST FOR USE IN THE MANUFACTURE OF POLYOLEFINS |
摘要 |
This invention provides a semi-continuous process and system thereof, for the synthesis of a narrow particle size distribution Zeigler Natta procatalyst for use in the manufacture of polyolefins comprising of following steps: (a) mixing a reaction mixture essentially consisting of titanium compound having at least one titanium halogen bond and a chlorinated solvent in feed section; (b) charging a first reactor with said reaction mixture; (c) continuously removing excess reactants from said first reactor as a filtrate through a filtrate section placed at the bottom of said first reactor; (d) feeding said filtrate to at least one further reactor connected to said first reactor to retain the carried over fine particles from said first reactor; continuously removing excess reactants from said at least further reactor as a filtrate through a filtrate section placed at the bottom of said at least one further reactor and, if desired, feeding said filtrate to next said at least one further reactor; (e) repeating step (d) for n number of times in series, wherein reactors are arranged in series or parallel; (f) subjecting the said filtrate from the last of said at least one further reactor to a distillation section to remove impurities and recover the distillate; and continuously charging the distillate from the distillation section to the feed section; wherein a desired equilibrium between fresh and recovered distillate and a desired resultant concentration of reactant feed are maintained; and (g) optionally treating the residue from distillation section with an alkali to obtain titanium hydroxide and calcining said titanium hydroxide to obtain titanium oxide as a by product. |
申请公布号 |
WO2011077447(A3) |
申请公布日期 |
2011.08.11 |
申请号 |
WO2010IN00809 |
申请日期 |
2010.12.14 |
申请人 |
RELIANCE INDUSTRIES LIMITED;SINGALA, KAMLESH;SINGH, SAURABH;GUPTA, VIRENDRAKUMAR |
发明人 |
SINGALA, KAMLESH;SINGH, SAURABH;GUPTA, VIRENDRAKUMAR |
分类号 |
C08F4/652;B01J27/08;C08F4/649;C08F10/00 |
主分类号 |
C08F4/652 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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