SUPER-SOLUTION HOMOGENEOUS PROPYLENE POLYMERIZATION AND POLYPROPYLENES MADE THEREFROM

摘要

This invention relates to processes for producing an isotactic propylene homopolymer having more than 15 and less than 100 regio defects (sum of 2,1-erythro and 2,1-threo insertions and 3,1-isomerizations ) per 10,000 propylene units; a weight-averaged molecular weight of 35000 g/mol or more; a peak melting temperature of greater than 149 0C; an mmmm pentad fraction of 0.85 or more; a heat of fusion of 80 J/g or more; and a peak melting temperature minus peak crystallization temperature (Tmp-Tcp) of less than or equal to (0.907 times Tmp) minus 99.64 (Tmp-Tcp < (0.907xTmp) - 99.64), as measured in 0C on the homopolymer having 0 wt % nucleating agent.