发明名称 METHOD FOR INTRODUCTION AND RECLAMATION OF COBALT DURING HYDROFORMYLATION OF PROPYLENE
摘要 FIELD: chemistry. ^ SUBSTANCE: invention discloses introduction of cobalt in form of a cobalt salt solution into a process for hydroformylation of propylene performed in the presence of a cobalt catalyst, where the said cobalt salt solution is specifically cobalt butyrate dissolved in a high-boiling azeotropic mixture of dimethyl acetamide (DMA) and dimethyl formamide (DMF) in butyric acid. Regeneration of a catalyst which is a mixture of cobalt butyrate and the azeotropic mixture of DMA and DMF with butyric acid is performed by treating the still residue after distillation of the end products with water, followed by stripping off the obtained aqueous extract and returning the stripped off residue to the hydroformylation step. ^ EFFECT: simple hydroformylation process. ^ 2 ex
申请公布号 RU2424224(C2) 申请公布日期 2011.07.20
申请号 RU20090136213 申请日期 2009.10.01
申请人 OBSHCHESTVO S OGRANICHENNOJ OTVETSTVENNOST'JU "OKSOKHIMNEFT'" 发明人 PETROV ANATOLIJ NIKOLAEVICH;SOKOLOV BORIS GENNAD'EVICH;BORISOV RIM BORISOVICH;JUGOV KONSTANTIN NIKOLAEVICH;KHOMJAKOV ALEKSANDR VLADIMIROVICH;NUZHDIN IGOR' ANATOL'EVICH;EL'KIN ALEKSANDR LEONIDOVICH;ZARIPOV MARAT SAGITOVICH
分类号 B01J23/75;B01J23/94;C07C45/50;C07C47/02 主分类号 B01J23/75
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