发明名称 Method for synthesizing optically active carbonyl compounds
摘要 The present invention relates to a process for preparing optically active carbonyl compounds by asymmetrically hydrogenating α,&bgr;-unsaturated carbonyl compounds in the presence of optically active transition metal catalysts which are soluble in the reaction mixture and have at least one carbon monoxide ligand, the optically active catalyst which has at least one carbon monoxide ligand and is to be used in each case being prepared by pretreating a catalyst precursor with a gas mixture comprising carbon monoxide and hydrogen and the asymmetric hydrogenation being performed in the presence of carbon monoxide supplied additionally to the reaction mixture.
申请公布号 US7973198(B2) 申请公布日期 2011.07.05
申请号 US20080597025 申请日期 2008.04.17
申请人 BASF SE 发明人 SCHMIDT-LEITHOFF JOACHIM;JAEKEL CHRISTOPH;PACIELLO ROCCO
分类号 C07C45/62 主分类号 C07C45/62
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