发明名称 Method for removing copper sulphide (cu2s) deposited onto cellulose-based material in transformer
摘要 A method for removing copper sulphide (Cu 2 S) deposited onto electrically insulating materials of components in an electrical apparatus, such as a transformer or a bushing, wherein normally present electrically insulating oil has been substantially removed, and on other surfaces of such apparatus, comprising the following steps: providing a chemical treatment solution comprising a polar aprotic solvent, and preferably a chelating agent being able of forming complexes with copper from the surface of Cu 2 S deposited onto the insulating material, said chelating agent containing free electrons capable of forming a complexation with Cu, being at least a bidentate, but preferably a multidentate, i.e. being able of forming complexes with Cu from more than one point in the chelating agent, and having a solubility in the polar aprotic solvent of at least 5·10 -4 mol/L to allow extraction of copper by solvation of the formed copper-chelating complex; and optionally additional components, said chemical treatment solution being non-aqueous; subjecting the insulating material to the solution, preferably at a temperature of 30-130 °C, more preferably 50-90°C, for a predetermined time period, preferably 2 to 10 days, more preferably 3 to 7 days; and removing the chemical treatment solution from the insulating material.
申请公布号 EP2333043(A1) 申请公布日期 2011.06.15
申请号 EP20090178180 申请日期 2009.12.07
申请人 ABB RESEARCH LTD. 发明人 GELLERSTEDT, GOERAN;BERGER, ROLF;PITOIS, CLAIRE;DAHLUND, MATS
分类号 C11D3/30;C11D11/00;C11D3/20;C11D3/28;C11D3/33;C11D3/36;C11D3/43 主分类号 C11D3/30
代理机构 代理人
主权项
地址