发明名称 METHOD FOR PRODUCING AQUEOUS STYRENE-BUTADIENE POLYMER DISPERSIONS III
摘要 The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by the radical aqueous emulsion-polymerisation of a monomer mixture M, containing: between 40 and 80 wt. % styrene as monomer M1; between 20 and 60 wt. % butadiene as monomer M2 and between 0 and 40 wt. %, (in relation to l00 wt. % monomers), of ethylenically unsaturated comonomers M3 that differ from styrene and butadiene, according to a monomer feed process in the presence of between 0.05 and 0.5 wt. %, (in relation to l00 wt. % monomers), of at least one hydrocarbon KW comprising between 6 and 20 C atoms, selected from compounds, which form a pentadienyl or a 1-phenylallyl radical during the abstraction of a hydrogen atom, or from .alpha.-methylstyrene dimers. Said method is characterised in that at least 30 % of the hydrocarbon KW is already present in the polymerisation vessel and the residual quantity of the hydrocarbon KW is fed to the polymerisation reaction during the course of the latter.
申请公布号 CA2461947(C) 申请公布日期 2011.05.24
申请号 CA20022461947 申请日期 2002.09.30
申请人 BASF AKTIENGESELLSCHAFT 发明人 GASCHLER, WOLFGANG;SCHAEDLER, VOLKER;MANDERS, LAMBERTUS;WIRTH, THOMAS;KROENER, HUBERTUS
分类号 C08F2/22;C08F212/08;C08F2/38;C08F212/00;C08F236/00;C08F236/06;C08F236/10;C08F291/00 主分类号 C08F2/22
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