发明名称 THERMOPLASTIC POLYOLEFINS WITH HIGH FLOWABILITY AND EXCELLENT SURFACE QUALITY PRODUCED BY A MULTISTAGE PROCESS
摘要 Reactor grade thermoplastic polyolefins with high flowability and excellent surface quality comprising (A) 40-90 wt % of a propylene homo- or copolymer matrix with an MFR in accordance with ISO 1 133 (230° C., 2.16 kg load) of >200 g/10 min and (B) 2-30 wt % of an elastomeric ethylene-propylene copolymer having an intrinsic viscosity IV (according to ISO 1628 with decalin as solvent) of ≦̸2.8 dl/g and an ethylene content of >50 to 80 wt % and (C) 8-30 wt % of an elastomeric ethylene-propylene copolymer having an intrinsic viscosity IV (according to ISO 1628 with decalin as solvent) of 3.0-6.5 dl/g and an propylene content of 50 to 80 wt %, the reactor grade thermoplastic polyolefins being obtainable by a multistage polymerization process with at least 3 polymerization steps in the presence of a catalyst system comprising (i) a Ziegler-Natta procatalyst which contains a trans-esterification product of a lower alcohol and a phthalic ester and (ii) an organometallic cocatalyst and (iii) external donor represented by formula (I) Si(OCH2CH3)3(NR1R2) wherein R1 and R2 can be the same or different a represent a hydrocarbon group having 1 to 12 carbon atoms, as well as the use of these reactor grade thermoplastic polyolefins and molded articles produced from them.
申请公布号 US2011086970(A1) 申请公布日期 2011.04.14
申请号 US20090737147 申请日期 2009.06.12
申请人 BOREALIS AG 发明人 GREIN CHRISTELLE;BERNREITNER KLAUS
分类号 C08L23/16;B01J31/12 主分类号 C08L23/16
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