发明名称 METHOD FOR PRODUCING OPTICALLY ACTIVE ETHYL 1-AMINO-2-ETHENYLCYCLOPROPANE-1-CARBOXYLATE OR ACID ADDITION SALT THEREOF, AND INTERMEDIATE USED FOR THE PRODUCTION METHOD
摘要 PROBLEM TO BE SOLVED: To provide a method for producing optically active ethyl 1-amino-2-ethenylcyclopropane-1-carboxylate. SOLUTION: The method for producing optically active ethyl 1-amino-2-ethenylcyclopropane-1-carboxylate represented by formula (3) or an enantiomer thereof, or an acid addition salt thereof, comprises a process for bringing a mixture comprising (1R, 2S) and (1S, 2R) isomers of ethyl 1-amino-2-ethenylcyclopropane-1-carboxylate into contact with a specific optically active tartranilic acid compound to produce a diastereomer salt mixture, a process for separating one of the diastereomer salts from the other, and a process for bringing the separated one diastereomer salt into contact with an acid or a base to hydrolyze the separated one diastereomer salt. COPYRIGHT: (C)2011,JPO&INPIT
申请公布号 JP2011046613(A) 申请公布日期 2011.03.10
申请号 JP20090193914 申请日期 2009.08.25
申请人 SUMITOMO CHEMICAL CO LTD 发明人 YASUOKA JUNICHI;AIKAWA TOSHIAKI;IKEMOTO TETSUYA
分类号 C07C227/34;C07B57/00;C07C229/48;C07C235/16 主分类号 C07C227/34
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