发明名称 |
MIXED MATRIX MEMBRANES WITH PYROLIZED CARBON SIEVE PARTICLES AND METHODS OF MAKING THE SAME |
摘要 |
<p>Mixed matrix polymer membranes capable of separating carbon dioxide from mixtures including carbon dioxide and methane, and processes for purifying methane using the membranes include a selective layer thickness of between about 1000 Angstroms to about 0.005 inch, that include discrete carbon-based molecular sieve particles with sizes of between about 0.5 microns to about 5.0 microns. The particles are formed by pyrolyzing a precursor polymer in the form of a powder or film. The pyrolyzed polymer is then ideally milled to desired small size particles. The preferred ratio of particles to polymer is about 0.25 to about 1.0 by volume. A preferred method for preparing the mixed matrix membrane is by dispersing the particles in a solvent, adding a small quantity of the desired polymer, or "sizing agent" to "size" or "prime" the particles, adding a polymer, casting a film of the polymer solution, and evaporating the solvent to form a mixed matrix membrane film. The polymer is preferably a rigid, glassy polymer, more preferably, with a glass transition temperature above about 150 DEG C. The mixed matrix membrane is preferably in the form of a dense film or a hollow fiber.</p> |
申请公布号 |
EP1335788(B1) |
申请公布日期 |
2011.02.23 |
申请号 |
EP20010973291 |
申请日期 |
2001.09.19 |
申请人 |
CHEVRON U.S.A. INC.;THE UNIVERSITY OF TEXAS SYSTEM |
发明人 |
KOROS, WILLIAM, J.;VU, DE, Q.;MAHAJAN, RAJIV;MILLER, STEPHEN, J. |
分类号 |
B01D53/22;B01D69/08;B01D69/14;B01D71/02;B01D71/12;B01D71/14;B01D71/16;B01D71/26;B01D71/28;B01D71/32;B01D71/38;B01D71/40;B01D71/42;B01D71/44;B01D71/48;B01D71/50;B01D71/52;B01D71/54;B01D71/64;B01D71/66;B01D71/68;B01J20/20;B01J20/28 |
主分类号 |
B01D53/22 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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