发明名称 METHOD FOR PRODUCING ALIPHATIC POLYESTER RESIN, AND AN ALIPHATIC POLYESTER RESIN COMPOSITION
摘要 An aliphatic polyester resin having a high molecular weight and, in the preferred state, a high melting point, and excellent thermal stability and hue, and a method for effectively producing the same are provided. A method for producing an aliphatic polyester resin including a melt polymerization step and a subsequent solid phase polymerization step, using a sulfonic acid group-containing compound as a catalyst, wherein the addition amount of the sulfonic acid group-containing compound during melt polymerization is 300 to 3000 ppm with respect to a raw material monomer calculated as sulfer atoms, the content of the sulfonic acid group-containing compound during melt polymerization is 300 to 3000 ppm with respect to a produced polymer calculated as sulfer atoms, and a residual rate of the sulfonic acid group-containing compound after solid phase at polymerization is more than 50%. Further, an aliphatic polyester resin composition containing a sulfonic acid group-containing compound having 2 or more sulfonic acid groups in one molecule in an aliphatic polyester resin, in a content of 300 to 3000 ppm with respect to a produced polymer calculated as sulfur atoms.
申请公布号 EP2280036(A1) 申请公布日期 2011.02.02
申请号 EP20090750558 申请日期 2009.05.19
申请人 TORAY INDUSTRIES, INC. 发明人 NAGANO, TATSUYA;NASUNO, TOMOKO;OME, HIROYUKI;HE, YONG;YU, BO;ZHU, KEXIN;GUO, XIAO;ZUO, PUJING
分类号 C08G63/82;C08G63/06;C08L67/04;C08L101/16 主分类号 C08G63/82
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