发明名称 |
METHOD FOR PRODUCING ALIPHATIC POLYESTER RESIN, AND AN ALIPHATIC POLYESTER RESIN COMPOSITION |
摘要 |
An aliphatic polyester resin having a high molecular weight and, in the preferred state, a high melting point, and excellent thermal stability and hue, and a method for effectively producing the same are provided. A method for producing an aliphatic polyester resin including a melt polymerization step and a subsequent solid phase polymerization step, using a sulfonic acid group-containing compound as a catalyst, wherein the addition amount of the sulfonic acid group-containing compound during melt polymerization is 300 to 3000 ppm with respect to a raw material monomer calculated as sulfer atoms, the content of the sulfonic acid group-containing compound during melt polymerization is 300 to 3000 ppm with respect to a produced polymer calculated as sulfer atoms, and a residual rate of the sulfonic acid group-containing compound after solid phase at polymerization is more than 50%. Further, an aliphatic polyester resin composition containing a sulfonic acid group-containing compound having 2 or more sulfonic acid groups in one molecule in an aliphatic polyester resin, in a content of 300 to 3000 ppm with respect to a produced polymer calculated as sulfur atoms. |
申请公布号 |
EP2280036(A1) |
申请公布日期 |
2011.02.02 |
申请号 |
EP20090750558 |
申请日期 |
2009.05.19 |
申请人 |
TORAY INDUSTRIES, INC. |
发明人 |
NAGANO, TATSUYA;NASUNO, TOMOKO;OME, HIROYUKI;HE, YONG;YU, BO;ZHU, KEXIN;GUO, XIAO;ZUO, PUJING |
分类号 |
C08G63/82;C08G63/06;C08L67/04;C08L101/16 |
主分类号 |
C08G63/82 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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