| 摘要 |
<p>To properly adjust a speed of vulcanization reaction without using a vulcanization retardant. ! This rubber complex uses a sulfenic amide compound as a vulcanization accelerator. The rubber complex is manufactured by a direct vulcanization adhesive method, by using amine generated from a sulfenic amide compound calculated by using a semi-experiential molecular orbital calculation method and a sulfenic amide-based vulcanization accelerator in which a bond order with a surface of a metallic material is 0, a bond distance of S-N(an amine part) of the sulfenic amide compound calculated by using a nonexperiential molecular orbital calculation method is less than 1.67 Å, and N electric charge of an amine radical generated as a result of dissociating an S-N bond is -0.295 or less. ! (C)2011,JPO&INPIT</p> |
