摘要 |
<p><P>PROBLEM TO BE SOLVED: To provide a solid polymer electrolyte membrane in which a proton conductive polymer material is filled in pores of a porous film, and which has low methanol permeability and is effective for a DMFC. <P>SOLUTION: This invention relates to an electrolyte membrane in which a proton conductive polymer material, in which the molar ratio of a unit derived from a monomer and having at least proton acid radical and a unit derived from a monomer, containing a nitrogen atom in the molecule and having no proton acid radical is 95:5-50:50, is filled into a porous film of low cost such as polyimide of which pore diameter formed by ion punching is 0.3μm or less and the elastic modulus is 1,000 MPa or more. The solid polymer electrolyte membrane has a low methanol permeability, without requiring a complicated process. <P>COPYRIGHT: (C)2011,JPO&INPIT</p> |