发明名称 Reaction Reagent for Trifluoromethylation
摘要 Provided is a reaction reagent for trifluoromethylation with high general versatility and good efficiency. The reaction reagent for trifluoromethylation contains an iron compound, trifluoromethyl iodide, a sulfoxide and a peroxide, and may further contain an acid. The iron compound is, for example, iron(II) sulfate, ammonium iron(II) sulfate, iron(II) tetrafluoroborate, ferrocene, bis(&eegr;5-pentamethylcyclopentadienyl)iron or an iron powder; the sulfoxide is, for example, dimethyl sulfoxide; the peroxide is, for example, hydrogen peroxide or hydrogen peroxide-urea composite; and the acid is, for example, sulfuric acid, tetrafluoroboric acid or trifluoromethanesulfonic acid.
申请公布号 US2010230633(A1) 申请公布日期 2010.09.16
申请号 US20070225249 申请日期 2007.11.06
申请人 YAMAKAWA TETSU;YAMAMOTO KYOKO;URAGUCHI DAISUKE;TOKUHISA KENJI 发明人 YAMAKAWA TETSU;YAMAMOTO KYOKO;URAGUCHI DAISUKE;TOKUHISA KENJI
分类号 C09K3/00 主分类号 C09K3/00
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