| 摘要 |
Provided is a cathode material for a lithium secondary battery composed of an aggregate of Li-A-0 composite oxide particles (wherein A represents one or more metal elements selected from Mn, Fe, Co and Ni), wherein the lithium composite oxide contains 20 to 100ppm (by mass) of P, and the total content of impurity elements excluding essential components is 2000ppm or less. Also provided is a manufacturing method of such a cathode material for a lithium secondary battery including the steps of suspending lithium carbonate in water and thereafter introducing a metallic salt solution of one or more metal elements selected from Mn, Fe, Co and Ni in the lithium carbonate suspension, adding a small amount of phosphoric acid so that the P content in the Li-A-O composite oxide particles will be 20 to 100ppm (by mass), and forming an aggregate of Li-A-O composite oxide particles containing 20 to 100ppm (by mass) of P by filtering, cleansing, drying and thereafter oxidizing the obtained carbonate. This cathode material for a lithium secondary battery and its manufacturing method realize improved sinterability and battery characteristics. |
