发明名称 A PROCESS FOR THE PREPARATION OF BIS-BENZAZOLYL COMPOUNDS
摘要 The present invention provides a process for the preparation of a compound of formula (I) wherein Y represents -O-, -S- or -N(R2)-, R2 being hydrogen, C1-C10alkyl or aralkyl; Z represents a 2,5-furanyl, 2,5-thiophenyl, 4,4'-stilbenyl or a 1,2-ethylenyl residue and R1 represents hydrogen, halogen, C1-C10alkoxyl, cyano, COOM or SO3M, M being hydrogen or an alkaline or alkaline earth metal, characterized by reacting a compound of formula (II) with a dicarboxylic acid of formula (III): HOOC-Z-COOH, or an ester thererof, Y, Z and R1 being as previously defined, in N-methylpyrrolidone or N,N-dimethylacetamide, in the presence of an acidic catalyst and, optionally, in the presence of a secondary solvent capable of removing water from the reaction mixture, which are useful as optical whitening agents for natural and synthetic materials.
申请公布号 CA2425165(C) 申请公布日期 2010.08.03
申请号 CA20012425165 申请日期 2001.10.09
申请人 CIBA SPECIALTY CHEMICALS HOLDING INC. 发明人 ELIU, VICTOR PAUL;HAUSER, JULIA
分类号 C07D263/62;C07B61/00;C07D235/20;C07D263/64;C07D277/66;C07D405/14;C07D413/14;C07D417/14 主分类号 C07D263/62
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