发明名称 Heteroatom bridged metallocene compounds for olefin polymerization
摘要 This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.
申请公布号 US7763562(B2) 申请公布日期 2010.07.27
申请号 US20050302998 申请日期 2005.12.14
申请人 EXXONMOBIL CHEMICAL PATENTS INC. 发明人 VOSKOBOYNIKOV ALEXANDER Z.;IZMER VYATCHESLAV V.;ASACHENKO ANDREY F.;NIKULIN MIKHAIL V.;RYABOV ALEXEY N.;LEBEDEV ARTYOM Y.;COKER CATALINA L.;CANICH JO ANN M.
分类号 C08F4/64;B01J31/22;C07F17/00;C08F4/6392;C08F4/6592 主分类号 C08F4/64
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