发明名称 SOLID TITANIUM CATALYST COMPONENT, OLEFIN POLYMERIZATION CATALYST, AND OLEFIN POLYMERIZATION METHOD
摘要 <p>The present invention provides an olefin polymerization catalyst, which is free of polyfunctional aromatic compounds and has a large particle diameter, and a solid titanium component (I) which forms the catalyst. The olefin polymerization catalyst comprises a solid titanium component (I), an organometallic compound (II) and optionally an electron donor (III) wherein the solid titanium component (I) comprising titanium, magnesium and halogen is obtainable by allowing a magnesium compound (A) having no reducing ability in a liquid state to contact with an ester compound (B) represented by the following formula (1) and a liquid titanium compound (C) in a specific order, wherein R 2 and R 3 are COOR 1 or R, and at least one of R 2 and R 3 is COOR 1 , two or more R 1 each are a monovalent hydrocarbon group having 1 to 20 carbon atoms, and two or more R are a hydrogen atom, or a hydrocarbon group having 1 to 20 carbon atoms, and at least two of Rs may be bonded each other to form a ring, and the skeleton of the ring formed may include a double bond or a hetero atom.</p>
申请公布号 EP2206731(A1) 申请公布日期 2010.07.14
申请号 EP20080846191 申请日期 2008.10.31
申请人 MITSUI CHEMICALS, INC. 发明人 MATSUNAGA, KAZUHISA;TSURU, KAZUTAKA;KAWAKITA, KAZUMITSU;JINNAI, TAKASHI;SHINOZAKI, TETSUNORI
分类号 C08F4/654;C08F4/651;C08F110/06 主分类号 C08F4/654
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