发明名称 Complex of Ruthenium and Osmium, Method of Production Thereof and Use Thereof As (Pre)Catalysts of the Metathesis Reaction
摘要 Complexes of ruthenium and osmium according to the invention are represented by formula (1), in which M denotes ruthenium or osmium, L denotes a neutral ligand selected from the group comprising amines, imines, phosphines (preferably stilbines, arsines, alcohols, thiols, ethers and thioethers or an N-heterocyclic carbene (NHC) ligand). The compounds of formula (1) occur in the form of two isomers: trans and cis. The method of production of complexes of ruthenium and osmium of formula (1) according to the invention is based on reacting an intermediate of formula (5) with a carbene complex of ruthenium or osmium. The invention also relates to the use of the complexes according to the invention for carrying out metathesis reactions.
申请公布号 US2010174068(A1) 申请公布日期 2010.07.08
申请号 US20070303615 申请日期 2007.06.01
申请人 UMICORE AG & CO KG 发明人 GRELA KAROL;BARBASIEWICZ MICHAL;SZADKOWSKA ANNA
分类号 C07F15/00 主分类号 C07F15/00
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