发明名称 Optically active 3-methylcyclopentadecanone and method for producing intermediate thereof
摘要 Disclosed is a method for producing an optically active 3-methylcyclopentadecan-1-one which is characterized in that 2-cyclopentadecen-1-one is subjected to a 1,4-conjugate addition reaction of a methyl group by using a methylated organic metal in the presence of a copper catalyst, an enol anion scavenger and a specific optically active phosphoramidite for obtaining an optically active 3-methyl-1-cyclopentadecene derivative, and then the thus-obtained 3-methyl-1-cyclopentadecene derivative is subjected to a solvolysis.
申请公布号 US7728177(B2) 申请公布日期 2010.06.01
申请号 US20060920600 申请日期 2006.05.17
申请人 TAKASAGO INTERNATIONAL CORPORATION 发明人 TANAKA SHIGERU;ISHIDA KENYA;MATSUDA HIROYUKI
分类号 C07C45/00 主分类号 C07C45/00
代理机构 代理人
主权项
地址