发明名称 |
Method of producing diol, polydiol, secondary alcohol or diketone compound |
摘要 |
The invention is a process of using, as a reducing agent, a 12CaO.7Al2O3 electride containing electrons in a number of 1019 or more and 2.3×1021 cm−3 or less in its cages to subject a carbonyl compound to reductive coupling in a solvent, thereby synthesizing a diol or polydiol. The invention is also a process of reducing a ketone compound in a solvent, thereby synthesizing a secondary alcohol or diketone compound. According to the process of the invention, it is possible to synthesize a diol or polydiol, or a secondary alcohol or diketone compound through simple operations in a short period without using an expensive and harmful metal hydride or metal salt nor limiting the atmosphere for the synthesis to an inert gas atmosphere as in conventional processes.
|
申请公布号 |
US7696386(B2) |
申请公布日期 |
2010.04.13 |
申请号 |
US20070441780 |
申请日期 |
2007.09.28 |
申请人 |
JAPAN SCIENCE AND TECHNOLOGY AGENCY |
发明人 |
HOSONO HIDEO;BUCHAMMAGARI HARITHA;TODA YOSHITAKE;HIRANO MASAHIRO;OSAKADA KOHTARO;TAKEUCHI DAISUKE |
分类号 |
C07C45/00;C07C29/16;C07C31/18 |
主分类号 |
C07C45/00 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|