发明名称 Halogenation of rylen-carboximides with elementary halogen in a two-phase mixture comprising an organic solvent and water, wherein formed halogen hydroxide is continuously removable from the organic solvent
摘要 A process for preparing halogenated rylenecarboximides of the general formula I in which the variables are each defined as follows: A, B together are an imide radical or, in the case that n is 1, A and B are also each Hal or one radical is Hal and the other radical is halogen; R, R′ are each independently hydrogen; optionally substituted alkyl, cycloalkyl, aryl or hetaryl; Hal is chlorine, bromine or iodine; n is 1, 2 or 3; x is from 2 to 8, by reacting a rylenecarboximide of the general formula II in which the A′ and B′ radicals together are an imide radical or, in the case that n is 1, are also each hydrogen with elemental halogen in the presence of an inert organic solvent S1, which comprises continuously withdrawing the hydrogen halide formed in the course of the reaction from the solvent S1.
申请公布号 US7678907(B2) 申请公布日期 2010.03.16
申请号 US20050576157 申请日期 2005.09.28
申请人 BASF AKTIENGESSELLSCHAFT 发明人 KOENEMANN MARTIN;PSCHIRER NEIL GREGORY
分类号 C07D221/18 主分类号 C07D221/18
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