| 摘要 |
Catalyst based reactions are taught for non-oxidative chemical conversion of liquid alcohols to higher boiling alcohols, ethers, glycol ethers, amines and oxygenated gasoline products, comprising ethanol to butanol, propanols to hexanols, butanols to octanols, ethanol plus butanol to ethyl butyl ethers, ethanol plus ethyl butyl ethers to ethyl hexyl ethers as oxygenated gasoline, ethanol plus ethyl hexyl ethers to butyl hexyl ethers as oxygenated gasoline, n-butyl amine plus ethanol to ethyl butyl amine, hexyl amines and related products at ambient pressure. This same catalytic chemistry also converts substituted liquid organic compounds comprising aldehydes, ketones, ethers, esters, organic acids and thiols possessing at least one active hydrogen to related alkylated organic products in the absence of air. Catalysts are based on selected transition metal complexes possessing a degree of symmetry. Laboratory results have demonstrated [chromium(II)]2, [cobalt(II)]2, [vanadium(II)]2 and similar families of catalysts to be effective for non-oxidative catalytic conversion of substituted organic compounds to products comprising related higher molecular weight compounds in good yields in the absence of air, at modest temperatures and pressures. |
