| 摘要 |
The inventive method, for producing a fumigant gas in the form of a mixture of phosphine and carbon dioxide, is carried out in a two-chamber reactor and involves introducing initial reagents, i.e. metal phosphide, an agent for releasing carbon dioxide during a chemical endothermic process and a binder in the first chamber, and an acid aqueous solution is into the second chamber, adding the acid aqueous solution to the reagents in the first chamber so as to simultaneously obtain phosphine and carbon dioxide and to compensate heat, which is released during phosphine production, by means of the chemical endothermic process of the carbon dioxide formation, wherein an agent which contribute to the matter loosening, contains a mixture of hydroxycarboxylic or dicarboxylic acid with a hydrophobic compound and the reaction of which with the mixture, formed during the process, generates carbon dioxide release, is introduced into the lower layers of the mixture in the first chamber. The mean rate of the gas fumigant production process is set up by opening a specified number of side apertures made on the side surface of a vertical channel according to the relationship between the diameter of a side aperture and the inner diameter of the vertical channel. The inventive method makes it possible to reduce the time required for producing the fumigant gas at the final stage of the process, to adjust the rate of the gas fumigant production process according to the conditions and a fumigation object, to simplify the start-up the fumigant gas producing device, simplify the preservation of the composition and hermeticity of the metal phosphide-containing mixture during the storage thereof and simultaneously to ease the formation of a free volume above the surface of the metal phosphide-containing mixture. |
