发明名称 PRODUCTION METHOD OF ALPHA-OLEFIN LOW POLYMER
摘要 The object of the present invention is to provide a production method of an alpha-olefin low polymer, wherein a low polymer of an alpha-olefin is obtained in high yield. The present invention relates to that when an inert gas is allowed to exist in a gas phase part of a reactor 10 in the proportion of from 0.010 to 50.00% by volume, and an alpha-olefin is subjected to low polymerization reaction in a solvent in the presence of a chromium series catalyst comprising a chromium compound (a), at lest one nitrogen-containing compound (b) selected from the group consisting of an amine, an amide and an imide, and an aluminum-containing compound (c), an unreacted alpha-olefin and the solvent separated from a reaction liquid are circulated into the reactor 10, and where the proportion of the inert gas in the gas phase exceeds 50.00% by volume, the inert gas is discharged outside the reaction system from a gas phase part of the reactor 10 and/or a circulation piping 21 of an unreacted alpha-olefin.
申请公布号 US2009326297(A1) 申请公布日期 2009.12.31
申请号 US20070520096 申请日期 2007.10.22
申请人 MITSUBISHI CHEMICAL CORPORATION 发明人 EMOTO HIROKI;YOSHIZURU KEI
分类号 C07C2/08 主分类号 C07C2/08
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